Photocatalytic Abstraction of Hydrogen Atoms from Water Using Hydroxylated Graphitic Carbon Nitride for Hydrogenative Coupling Reactions

نویسندگان

چکیده

Employing pure water, the ultimate green source of hydrogen donor to initiate chemical reactions that involve a atom transfer (HAT) step is fascinating but challenging due its large H-O bond dissociation energy (BDE = 5.1 eV). Many approaches have been explored stimulate water for hydrogenative reactions, efficiency and productivity still require significant enhancement. Here, we show surface hydroxylated graphitic carbon nitride (gCN-OH) only requires 2.25 eV activate bonds in enabling abstraction atoms via dehydrogenation into peroxide under visible light irradiation. The gCN-OH presents stable catalytic performance N-N coupling, pinacol-type coupling dehalogenative C-C all with high yield efficiency, even solar radiation, featuring extensive impacts using renewable cleaner process dye, electronic, pharmaceutical industries.

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2022

ISSN: ['1521-3773', '1433-7851', '0570-0833']

DOI: https://doi.org/10.1002/ange.202204256